Zinc anodes are installed to protect expensive underwater metal from galvanic corrosion. A galvanic cell is formed by two or more, “dissimilar” metals (your zinc anode is one-half a galvanic cell); electrically connected together, (the bonding system or direct contact provide this electrical connection); immersed in a common electrolyte (the ocean). The difference in electrical potential of the two metals causes an electrical current to flow. The electrons in this flow come from the destruction (corrosion) of molecules from the “least noble” (more negative) metal (the anode). These electrons flow through the electrical connection between the two metals to the “cathode,” then combine with ions in the electrolyte to flow back to the anode to complete the circuit. By selecting the metal used for the anode, we can control which metal corrodes and which metal is protected (Cathodic Protection). Any other metals in the electrolyte not electrically connected to this cell are in “free corrosion” and will not affect your zincs (anode).
Stray current is similar to galvanic corrosion in that the corrosion is driven by a difference in electrical potential. With stray current, the difference is caused by an external power supply. The size of this difference can cause severe corrosion to occur in weeks, days, or in extreme cases, even hours.
A galvanic isolator can protect your boat from galvanic corrosion caused by other boats connected to the same shore power system. These devices are highly recommended for boats living in marinas connected to shore power. Unfortunately, they can be overcome by stray current rendering them useless.
Marinas are difficult places to evaluate galvanic and stray current corrosion because they are dynamic. The level of corrosion can vary with the number of boats present and/or connected to the system. If you find you have a problem one day but not the next, it helps to try to determine what boats are present when the problem is evident.
There are electrical tests that can evaluate the level of corrosion and determine if it is galvanic or stray current. These tests can also be used to help identify the source of the stray current. It is also possible that stray current from nearby boats in a marina to cause corrosion on your boat, even if your boat is not connected to the shore power system. In answer to Ed’s question, sticking the test lead of your meter in the water will some cases, expose stray current. The trick is to know where to connect the other test lead and to understand what it is telling you.
The Boatowner’s Guide to Corrosion, by Everett Collier is used as the textbook for the ABYC Corrosion Certification Class. While it does a thorough job to documenting the subject, it can be difficult to understand in some areas and does not detail the electrical tests used to identify problems.
I am an ABYC Certified Corrosion Technician and currently teach their corrosion certification classes. I worked as an engineer at Freedom Yachts and owned Freedom 36 #71 for many years. In addition to services as an independent marine surveyor, I am available to evaluate complex electrical and corrosion problems on all boats not just Freedoms.